Pearson Edexcel ChemistryAtmosphere and resources

Atmosphere and climate change

Describe the composition of the atmosphere and explain how human activity affects climate.

Start here

The key idea

The Earth's atmosphere is approximately 78% nitrogen, 21% oxygen and small amounts of other gases including CO₂ and water vapour.Greenhouse gases trap heat and maintain surface temperature, but increasing their concentration causes global warming.

Atmosphere And Climate
Sunlight ininfrared trappedEarth surface

Use the labels to explain the scientific relationship shown.

Revision notes

The bit that matters

Keep the idea tight, then use the worked example to practise the exact exam wording.

1

Composition of the atmosphere

04%) and water vapour.The early atmosphere of the Earth contained much more CO₂ and very little oxygen, similar to the current atmospheres of Mars and Venus.Over billions of years, photosynthesis produced oxygen and locked carbon away.

2

The greenhouse effect

Greenhouse gases (CO₂, CH₄, water vapour, N₂O) in the atmosphere absorb infrared radiation emitted by the Earth's warm surface and re-emit it in all directions, including back towards Earth.This natural greenhouse effect is essential for maintaining a temperature that supports life.Without it, Earth's surface temperature would be around −18°C.

3

Climate change

Human activities — burning fossil fuels, deforestation and intensive farming — have significantly increased the concentrations of CO₂ and CH₄ in the atmosphere.This enhances the greenhouse effect, causing global temperatures to rise.Consequences include melting ice caps, rising sea levels, more extreme weather, and disruption of ecosystems.Most scientists agree this is largely human-caused, but the full extent is still debated.

4

Development of the atmosphere over time

In the first billion years, volcanic activity released mainly CO₂, water vapour and nitrogen.As the Earth cooled, water vapour condensed to form oceans, and CO₂ dissolved in seawater to form carbonates.5 billion years ago steadily increased O₂ levels and reduced CO₂.The deposition of carbon in fossils and rocks locked away carbon dioxide permanently.

Key terms

Definitions to learn

Greenhouse gas

A gas that absorbs and re-emits infrared radiation, contributing to the greenhouse effect.

Greenhouse effect

The trapping of infrared radiation by atmospheric gases that keeps Earth's surface warm enough for life.

Global warming

The observed increase in average global temperature attributed largely to increased greenhouse gas concentrations.

Carbon footprint

The total amount of CO₂ and equivalent greenhouse gases emitted by an individual, product or activity.

Fossil fuel

A fuel (coal, oil, natural gas) formed from the remains of ancient organisms over millions of years.

Worked example

Explain the greenhouse effect and why it is important for life on Earth.

1

Short-wavelength radiation from the Sun passes through the atmosphere to warm the Earth's surface.

2

The surface re-emits longer-wavelength infrared radiation.

3

Greenhouse gases (CO₂, CH₄, water vapour) absorb some of this infrared radiation.

4

The gases re-emit energy in all directions, some back towards the Earth.

5

This keeps the Earth warmer than it would otherwise be, making life possible.

Final answer

Greenhouse gases trap infrared radiation and maintain Earth's temperature.

Exam habit

For greenhouse effect questions, always include both absorption of infrared radiation by greenhouse gases AND re-emission back towards the Earth.

Watch out

Do not confuse the greenhouse effect with ozone depletion. They are different atmospheric issues.

Examiner tips

How to score full marks

  • 1The greenhouse effect is NATURAL and ESSENTIAL for life — distinguish this from the ENHANCED greenhouse effect caused by human activity.
  • 2State the full mechanism: greenhouse gases absorb infrared radiation from Earth AND re-emit it back towards Earth.
  • 3When describing the early atmosphere, state that CO₂ was very high and O₂ was very low — opposite to today.
Practice questions

Try these yourself

Open each answer only after you have explained the full chemical process.

1State the approximate percentage of nitrogen and oxygen in the atmosphere.[2 marks]
Mark scheme
  1. 1.Recall the two main components.
Nitrogen: approximately 78% (1); Oxygen: approximately 21% (1).
2Name three greenhouse gases.[3 marks]
Mark scheme
  1. 1.Recall gases that absorb infrared radiation.
Any three from: carbon dioxide (1); methane (1); water vapour (1); nitrous oxide (1).
3Explain why burning fossil fuels increases the greenhouse effect.[4 marks]
Mark scheme
  1. 1.Link combustion to CO₂ and then to warming.
Burning fossil fuels releases carbon dioxide (1), which is a greenhouse gas (1); it absorbs infrared radiation from the Earth (1), trapping more heat in the atmosphere (1).
4Explain how the evolution of photosynthesising organisms changed the composition of the early atmosphere.[3 marks]
Mark scheme
  1. 1.Describe the changes in CO₂ and O₂ over time.
Early photosynthesising organisms absorbed carbon dioxide (1) and released oxygen (1); over billions of years, CO₂ levels fell and O₂ levels rose (1) to near the current levels.
5State the origin of nitrogen in the early atmosphere.[2 marks]
Mark scheme
  1. 1.Describe what produced it.
Nitrogen was released by volcanic activity (1) and denitrifying bacteria (1) over billions of years.
6Give two consequences of global warming for the planet.[2 marks]
Mark scheme
  1. 1.Think about sea level and weather patterns.
Any two from: rising sea levels (due to melting ice caps) (1); more extreme weather events (1); disruption of ecosystems/food chains (1); flooding of low-lying areas (1).
7Explain why it is difficult to reach conclusions about the extent of human influence on climate change.[3 marks]
Mark scheme
  1. 1.Consider the complexity of the evidence.
Climate data is complex and involves many variables (1); scientists disagree on how much is due to natural cycles versus human activity (1); some data is disputed (1); long-term records are incomplete (1).
8Describe two ways that carbon dioxide has been removed from the atmosphere over geological time.[2 marks]
Mark scheme
  1. 1.Identify natural processes that remove CO₂.
Photosynthesis by plants and algae absorbed CO₂ (1); CO₂ dissolved in oceans to form carbonates that were deposited in shells and sedimentary rocks (1); dead organisms formed fossil fuels, locking carbon underground (1). (Any two.)
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