AQA ChemistryChemical changes

Acids, bases and neutralisation

Define acids and alkalis in terms of pH, H⁺ ions and neutralisation reactions.

Start here

The key idea

Acids release H⁺ ions in solution; bases accept them. Neutralisation: acid + base → salt + water.The pH scale runs from 0 to 14; below 7 is acidic, 7 is neutral, above 7 is alkaline.

Equation to know

H⁺(aq) + OH⁻(aq) → H₂O(l)

Acids And Bases
acidneutralalkalipH 1pH 7pH 14

Use the labels to explain the scientific relationship shown.

Revision notes

The bit that matters

Keep the idea tight, then use the worked example to practise the exact exam wording.

1

The pH scale and ions

The pH scale measures the concentration of H⁺ ions in solution from 0 to 14.Acidic solutions have a pH below 7 and contain more H⁺ ions than OH⁻ ions; alkaline solutions have a pH above 7 and contain more OH⁻ ions; pure water is neutral at pH 7.The scale is logarithmic: a change of 1 pH unit represents a tenfold change in H⁺ concentration.

2

Strong and weak acids

g. hydrochloric, sulfuric, nitric) is completely dissociated in water, releasing all its H⁺ ions. g.ethanoic acid, citric acid) is only partially dissociated, so only a small fraction of the molecules release H⁺ ions.At the same concentration, a strong acid has a higher H⁺ concentration and a lower pH than a weak acid.

3

Neutralisation reactions

Neutralisation is the reaction of an acid with a base (or alkali) to form a salt and water.The ionic equation for all neutralisation reactions is H⁺(aq) + OH⁻(aq) → H₂O(l). g.sodium + chloride → sodium chloride).

4

Salts from different acids

Hydrochloric acid forms chloride salts; sulfuric acid forms sulfate salts; nitric acid forms nitrate salts.Bases used in neutralisation include metal oxides, metal hydroxides, metal carbonates and ammonia.A carbonate reacts with an acid to produce a salt, water and carbon dioxide.

Key terms

Definitions to learn

Acid

A substance that releases H⁺ ions in aqueous solution and has a pH below 7.

Base

A substance that neutralises an acid; a soluble base is called an alkali.

Alkali

A base that dissolves in water to produce OH⁻ ions; has a pH above 7.

Neutralisation

The reaction of an acid and a base to produce a salt and water.

Strong acid

An acid that is completely ionised in aqueous solution.

Weak acid

An acid that is only partially ionised in aqueous solution.

Worked example

Write the ionic equation for a neutralisation reaction.

1

Identify the ions produced: H⁺ from acid, OH⁻ from alkali.

2

These ions combine to form water.

3

Write: H⁺(aq) + OH⁻(aq) → H₂O(l)

Final answer

H⁺(aq) + OH⁻(aq) → H₂O(l)

Exam habit

For salt naming: the first word comes from the base (metal name), the second from the acid (chloride from HCl, sulfate from H₂SO₄, nitrate from HNO₃).

Watch out

Do not write 'acid + base → salt + water' as the only answer for 'write an ionic equation'.The ionic equation for neutralisation is always H⁺ + OH⁻ → H₂O.

Examiner tips

How to score full marks

  • 1The ionic equation for neutralisation is always H⁺ + OH⁻ → H₂O — learn this and use it every time.
  • 2Distinguish strong/weak (degree of ionisation) from concentrated/dilute (amount of solute) — these are different concepts.
  • 3Name salts systematically: metal name first (from the base), then acid's anion (chloride, sulfate, nitrate).
Practice questions

Try these yourself

Open each answer only after you have explained the full chemical process.

1State the pH range of an acid.[1 mark]
Mark scheme
  1. 1.Recall the pH scale.
Below 7 (1).
2Write the word equation for the reaction of hydrochloric acid with sodium hydroxide.[1 mark]
Mark scheme
  1. 1.Identify acid + base products.
hydrochloric acid + sodium hydroxide → sodium chloride + water (1).
3Give the name of the salt formed when sulfuric acid reacts with calcium hydroxide.[1 mark]
Mark scheme
  1. 1.Identify the acid's name and the metal in the base.
Calcium sulfate (1).
4Explain what is meant by a strong acid.[2 marks]
Mark scheme
  1. 1.Link to degree of ionisation.
A strong acid is fully (completely) ionised in aqueous solution (1), so it releases all its H⁺ ions (1).
5Explain why the pH of a strong acid is lower than that of a weak acid of the same concentration.[2 marks]
Mark scheme
  1. 1.Compare H⁺ ion concentrations.
A strong acid fully ionises so there is a higher concentration of H⁺ ions (1); a higher H⁺ concentration gives a lower pH (1).
6Describe a simple test to show a substance is an acid.[2 marks]
Mark scheme
  1. 1.State what you would add and what you would see.
Add universal indicator or use a pH probe (1); acids give a pH below 7 / a red or orange colour (1).
7Write a balanced symbol equation for the reaction of magnesium with hydrochloric acid.[2 marks]
Mark scheme
  1. 1.Identify the products of metal + acid.
Mg + 2HCl → MgCl₂ + H₂ (1) — must be balanced (1).
8Explain the difference between a strong acid and a concentrated acid.[4 marks]
Mark scheme
  1. 1.Link strength to ionisation and concentration to amount of solute.
Strength refers to how completely the acid ionises in water (1); a strong acid fully ionises (1). Concentration refers to the number of moles of acid per dm³ (1); these are independent properties (1).
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